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Scheme 3. Scope of 1,1-disubstituted aryl alkenes for ketone addition.a aThe same conditions as in Table 1; yield refers to the combined yield of two diastereomers, see the ESI† for details. bOne equivalent of alkene and two equivalents of ketone were used. cYield of the major diastereomer after oxidation with NaBO3·4H2O. dYield of the major diastereomer. e6h was used as the ligand.