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Evaluation of Conditions for the Oxidation of Homoallylic Alcohol 1ma
| ||||
|---|---|---|---|---|
| entry | %BQ | time (h) | yield (%) | unreacted 1m (%) |
| 1 | 0 | 1 | 28 | 46 |
| 2 | 0 | 3 | 28 | 47 |
| 3 | 0 | 48 | 25 | 0 |
| 4 | 5 | 1 | 70 | 0 |
| 5 | 10 | 1 | 70 | 0 |
| 6 | 50 | 1 | 69 | 0 |
| 7 | 10 | 3 | 69 | 0 |
Conditions: Reactions were conducted with 0.1 mmol (1 equiv) of 1m and 2.0 equiv of BzO2tBu. Yields were determined by 1H NMR.
