Table 1. A compilation of redox potentials obtained by square wave voltammetry of cross-linked pyrene-LPEI films containing 80 μg of protein per film. The same protein/hydrogel film preparation procedure was used for all proteins studied, and films were coated onto 0.25 cm2 Toray electrode without the addition of CNTs.
| Enzyme | Cofactor | pH | Redox potential, E/V vs. SCE |
||
| This work | Literature | Ref. | |||
| Laccase | Cu-l | 4.5 | –0.615 ± 0.007 | –0.556 | 25 |
| Cytochrome C | Heme | 7.0 | –0.200 ± 0.006 | –0.174 | 38 |
| MoFe protein (nitrogenase) | P-Cluster [8Fe–7S] | 7.0 | –0.512 ± 0.008 | –0.544 | 39 |
| Ferredoxin | [2Fe–2S] | 7.0 | –0.583 ± 0.003 | –0.609 | 38 |
| Flavodoxin | FMN | 7.0 | –0.727 ± 0.008 | –0.688 | 40 |
| Free FMN | FMN | 7.0 | –0.437 ± 0.003 | –0.462 | 40 |