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. 2016 Feb 12;7(5):2964–2986. doi: 10.1039/c6sc00188b

Fig. 4. Potential surfaces for (a) a bound excited state where the barrier is >kBT and (b) a dissociative ES where the barrier is <kBT. Since kBT is temperature dependent, if any barrier is present, an ES that is dissociative at a high T, may behave as a bound state at low T.

Fig. 4