Fig. 3. X-ray molecular structure of (9). The PtBu2 unit is disordered over 2 sites, only the major component labelled, i.e. P(1A), C(11A), is shown. [BArF4]– anion and selected hydrogen atoms omitted for clarity. Selected bond lengths (Å) and angles (°): P(1A)–B(1) 1.99(2), P(1B)–B(1) 1.901(14), B(1)–P(2) 1.918(5), Rh(1)–P(1A) 2.30(3), Rh(1)–P(1B) 2.258(14), Rh(1)–B(1) 2.431(5), Rh(1)–Cp* (centroid) 1.870; P(1A)–B(1)–P(2) 126.2(7).
