TABLE 3.
Storage condition | Autosampler at 4 °C | Freeze-thaw three cycles at −20°C | Bench-top at room temperature | Long-term stability at −20°C | Long-term stability at −80°C | ||||
---|---|---|---|---|---|---|---|---|---|
Matrix | Extracted matrix | Original matrix | Original matrix | Extracted matrix | Original matrix | Extracted matrix | Original matrix | ||
Time | Up to 24 h | Up to 3 cycles | Up to 2 h | Up to 8 h | Up to 4h | Up to 180 days | Up to 3 days | Up to 7 days | Up to 180 days |
Stock solution | 8 and 27 | 17 and 42 | All stable | 16 and 41 | NA | 16 and 41 | NA | NA | 16 and 41 |
Serum | 8 and 27 | 3, 15, 16, 18, 33, 36, 41, 42, 43 and 44 | 3, 15, 16, 41 and 42 | 3,15, 16, 18, 22, 33, 39, 41, 42, 43, 27 and 44 | All stable | 15,16, 18, 22, 33, 36, 38, 41, 42, 43 and 44 | 15, 16 | 1, 14, 15, 16, 33, 34 and 41 | NA |
Analytes with >20% loss by the reported time intervals under different storage conditions are presented.