Table 4. Catalytic parameters for 1–3 in CH3CN in the presence of HTFA at a catalyst-to-acid ratio of 1 : 100.
Catalytic parameters | 1 | 2 | 3 |
E(H+/H2) (V) vs. Fc/Fc+ | –1.03 | –1.04 | –1.03 |
Overpotential (V) (10 eq. HTFA) | 0.35 | 0.36 | 0.35 |
TON/3 h (4.0 × 10–5 mol) | 18.7 | 13.8 | 13.8 |
Faradaic efficiency (%) | 77 | 84 | 75 |