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. Author manuscript; available in PMC: 2018 Jun 19.
Published in final edited form as: ACS Catal. 2017 Apr 27;7(6):3916–3923. doi: 10.1021/acscatal.7b01286

Scheme 1.

Scheme 1

A mechanism of the O2 reduction by BODs based on Solomon et al.2,11 with our additions concerning the AR formation and reactivation in the presence of chloride ions. The catalytic cycle is drawn in blue, the non-catalytically relevant forms are drawn in green, and electrode induced redox changes are indicated in red.