Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
C–S bond formation through an ionic type of reaction in gliotoxin biosynthesis. In the gliotoxin 12 biosynthetic pathway, C–S bond formation mediated by GliG undergoes a nucleophilic attack by GSH on an acyliminium intermediate 5a, giving bis-glutathionylated intermediate 6.
