Table 3. Summary of calculated binding affinities, Ka (M–1) as determined by UV-Vis spectroscopy in two separate solvent systems a .
Anions a | 3b b | 3b c | 7b c |
H2PO4– | (8 ± 2) × 106 | (2.1 ± 0.3) × 103 | (1.4 ± 0.2) × 105 |
HP2O73– | (1.4 ± 0.1) × 105 | (3.8 ± 0.6) × 103 | (3.6 ± 0.2) × 104 |
HSO4– | (4.1 ± 0.2) × 103 | nd | nd |
NO3– | nd | nd | nd |
Cl– | nd | nd | nd |
aThe anions were studied as their TBA+ salts.
bIn CHCl3; data from ref. 24.
cIn CHCl3 containing 3% (v/v) CH3OH.