Table 1. Thermodynamic parameters for the self-assembly of C3OPV obtained using the isodesmic model a .
C3OPV | C (mM) | ΔH (kJ mol–1) | ΔS (J mol–1 K–1) | T m (K) | K e (104 M–1) | DPN |
Alone | 0.1 | –85.1 | –194.5 | 321.5 | 4.7 | 2.7 |
In the mixture | 0.1 | –73.6 | –158.0 | 321.2 | 3.7 | 2.5 |
a C is the concentration, ΔH is the change in enthalpy, ΔS is the change in entropy, Tm is the melting transition temperature, Ke is the association constant and DPN is the degree of polymerization.