Table 2. Thermodynamic parameters for the self-assembly of C3PBI obtained using the nucleation elongation model a .
C3PBI | C (mM) | ΔHe (kJ mol–1) | ΔSe (J mol–1 K–1) | T m (K) | T e (K) | K a |
Alone | 0.1 | –27.4 | –140.9 | 336.3 | 360.5 | 10–6 |
In the mixture | 0.1 | –27.5 | –132.6 | 335.9 | 362.4 | 10–6 |
a C is the concentration, ΔHe and ΔSe, respectively, are the change in enthalpy and entropy during the elongation process, Tm is the melting transition temperature, Te is the elongation temperature and Ka is the degree of cooperativity.