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. 2018 Apr 2;23(4):809. doi: 10.3390/molecules23040809

Table 4.

2 h Biotransformation of sulfides and styrene. Conversions of 2 mM substrate were analyzed.

Substrate Product VpStyA1 Conversion (%) ee (%) VpStyA2B Conversion (%) ee (%)
PMS graphic file with name molecules-23-00809-i001.jpg 43.6 ± 1.9 98 (S) 6.3 ± 0.3 64 (S)
4F-PMS graphic file with name molecules-23-00809-i002.jpg 59.8 ± 0.4 99 (S) 4.3 ± 0.7 84 (S)
4Cl-PMS graphic file with name molecules-23-00809-i003.jpg 38.5 ± 1.7 99 (S) 4.4 ± 0.4 96 (S)
4Br-PMS graphic file with name molecules-23-00809-i004.jpg 32.4 ± 4.7 99 (S) 6 ± 0.7 96 (S)
BMS graphic file with name molecules-23-00809-i005.jpg 95 ± 0.5 97 (S) 13 ± 0.9 n.d. (S)
Styrene graphic file with name molecules-23-00809-i006.jpg 9.9 ± 0.4 98.2 (S) 0.5 ± 0.1 45 (S)

Phenyl methyl sulfide (PMS; thioanisole), 4-fluoro phenyl methyl sulfide (4F-PMS), 4-chloro phenyl methyl sulfide (4Cl-PMS), 4-bromo phenyl methyl sulfide (4Br-PMS), benzyl methyl sulfide (BMS); n.d. = not detectable.