Table 1.

The detecting parameters of compounds in MRM mode for LC-MS/MS analysis.

Compound	Formula	tR (min)	MRM Transitions	Cone Voltage (V)	Collision Energy (eV)
SA5	C22H30O14	1.87	517.00→174.92	68	20
SA6	C23H32O15	2.09	547.02→204.96	66	24
SXB	C24H26O14	3.23	536.97→314.89	82	32
PXXI	C25H28O15	3.57	567.05→271.77	88	48
DS	C34H42O19	5.08	753.07→204.96	90	36
PGD	C57H92O27	5.67	1207.36→469.04	90	52
TF	C36H56O12	5.86	679.15→455.12	78	24
PGA	C29H44O6	6.20	487.16→469.13	76	30
SG	C30H45ClO6	6.24	535.20→481.09	56	32
Rg1 (IS)	C42H72O14	5.52	845.33→799.20	70	22