Table 1.
Compound | Calculated LRI * | Literature LRI * | 2015 | 2016 | Mean Values on Two Years | Reference Literature for LRI | |||
---|---|---|---|---|---|---|---|---|---|
% FID | σ | % FID | σ | % FID | σ | ||||
α-Pinene | 947 | 939 | 0.77 | 0.33 | 0.90 | 0.35 | 0.84 | 0.31 | [24] |
Sabinene | 981 | 975 | 0.71 | 0.27 | 0.32 | 0.28 | 0.51 | 0.33 | [24] |
Alpha terpinene | 1014 | 1017 | 0.16 | 0.04 | 0.18 | 0.07 | 0.17 | 0.06 | [24] |
p-Cymene | 1020 | 1024 | 2.57 | 0.85 | 4.85 | 111 | 3.71 | 1.53 | [24] |
γ-Terpinene | 1049 | 1059 | 0.73 | 0.19 | 0.92 | 0.35 | 0.83 | 0.27 | [24] |
Trans-sabinene hydrate | 1059 | 1070 | 0.27 | 0.09 | 0.38 | 0.03 | 0.32 | 0.08 | [24] |
Linalool | 1091 | 1096 | 0.15 | 0.05 | Trace | - | 0.08 | 0.09 | [24] |
Pinocarvone | 1148 | 1160 | 0.10 | 0.01 | Trace | - | 0.05 | 0.06 | [25] |
3-Pinanone | 1164 | 1168 | 3.82 | 1.11 | 1.84 | 1.73 | 2.83 | 1.69 | [26] |
4-Carvomenthenol | 1170 | 1177 | 0.24 | 0.11 | 0.23 | 0.06 | 0.23 | 0.08 | [27] |
Dihydro carveol | 1186 | 1194 | 0.43 | 0.14 | 0.29 | 0.10 | 0.36 | 0.13 | [24] |
Thymol methyl ether | 1227 | 1235 | 0.93 | 0.29 | 1.30 | 0.40 | 1.11 | 0.37 | [28] |
Carvacrol methyl ether | 1248 | 1244 | 18.87 | 3.89 | 23.35 | 5.66 | 21,11 | 4.99 | [24] |
Methyl carvacrol | 1254 | 1248 | Trace | - | 0.13 | 0.05 | 0.06 | 0.08 | [29] |
Piperitone | 1248 | 1252 | 0.25 | 0.10 | Trace | - | 0.13 | 0.15 | [24] |
Methylbenzoate | 1268 | 1271 | 0.12 | 0.03 | Trace | - | 0.06 | 0.07 | [30] |
Endobornyl acetate | 1281 | 1285 | 0.21 | 0.04 | Trace | - | 0.10 | 0.12 | [24] |
trans-pinocarvyl acetato | 1294 | 1298 | 2.13 | 0.46 | 0.66 | 0.91 | 1.39 | 1.03 | [24] |
Carvacrol | 1308 | 1299 | 13.81 | 2.01 | 16.26 | 0.65 | 15.04 | 1.89 | [24] |
Myrtenyl acetate | 1325 | 1326 | 0.91 | 0.16 | 0.42 | 0.19 | 0.66 | 0.31 | [24] |
Piperitenone | 1334 | 1343 | 0.16 | 0.02 | Trace | - | 0.08 | 0.09 | [24] |
δ-Elemene | 1337 | 1338 | 1.10 | 0.17 | Trace | - | 0.55 | 0.61 | [24] |
Unidentified | 1353 | - | Trace | - | 1.40 | 0.29 | 0.70 | 0.79 | - |
Carvacryl acetate | 1373 | 1371 | 11.35 | 1.42 | 14.82 | 1.66 | 13.08 | 2.35 | [31] |
β-Bourbonene | 1379 | 1388 | 0.22 | 0.06 | 0.27 | 0.05 | 0.25 | 0.05 | [24] |
Unidentified | 1387 | - | Trace | - | 0.07 | 0.06 | 0.04 | 0.06 | - |
β-Elemene | 1389 | 1390 | 0.21 | 0.05 | 0.12 | 0.01 | 0.16 | 0.06 | [24] |
Z-caryophyllene | 1414 | 1419 | 3.21 | 0.54 | 3.05 | 0.27 | 3.13 | 0.40 | [24] |
Unidentified | 1428 | - | 0.09 | 0.03 | 0.11 | 0.02 | 0.10 | 0.02 | - |
α-humulene | 1448 | 1449 | Trace | - | 0.12 | 0.01 | 0.06 | 0.06 | [32] |
Aromadendrene | 1452 | 1447 | 0.11 | 0.01 | 0.12 | 0.01 | 0.12 | 0.01 | [33] |
Unidentified | 1455 | - | 0.09 | 0.02 | Trace | - | 0.04 | 0.05 | - |
trans-β-farnesene | 1458 | 1456 | 0.09 | 0.02 | Trace | - | 0.04 | 0.05 | [24] |
Unidentified | 1468 | - | Trace | - | Trace | - | Trace | - | - |
Germacrene D | 1474 | 1484 | 1.59 | 0.27 | 1.81 | 0.16 | 1.70 | 0.23 | [24] |
β-selinene | 1480 | 1486 | Trace | - | Trace | - | Trace | - | [34] |
Ledene | 1484 | 1496 | Trace | - | Trace | - | Trace | - | [24] |
Unidentified | 1487 | - | 0.73 | 0.08 | 0.79 | 0.07 | 0.76 | 0.08 | - |
Unidentified | 1492 | - | Trace | - | 0.44 | 0.09 | 0.22 | 0.25 | [24] |
γ-cadinene | 1505 | 1513 | Trace | - | Trace | - | Trace | - | [27] |
Unidentified | 1508 | - | Trace | - | Trace | - | Trace | - | - |
δ-Cadinene | 1513 | 1523 | 0.61 | 0.14 | 0.65 | 0.01 | 0.63 | 0.09 | [24] |
Cadina-1,4-diene | 1524 | 1534 | Trace | - | Trace | - | Trace | - | [24] |
Selina-3,7(11)-dien | 1530 | 1537 | Trace | - | Trace | - | Trace | - | [35] |
Elemol | 1546 | 1549 | 9.05 | 2.60 | 4.79 | 1.24 | 6.92 | 2.96 | [24] |
Unidentified | 1566 | - | 0.35 | 0.10 | 0.23 | 0.09 | 0.29 | 0.11 | - |
Unidentified | 1577 | - | 0.79 | 0.28 | 0.55 | 0.22 | 0.67 | 0.26 | - |
Unidentified | 1592 | - | 2.34 | 1.12 | Trace | - | 1.17 | 1.46 | [24] |
Guaiol | 1601 | 1600 | 1.36 | 1.25 | 0.40 | 0.14 | 0.88 | 0.96 | [24] |
Agarospirol | 1620 | 1631 | 8.02 | 3.89 | Trace | - | 4.01 | 5.03 | [36] |
β-Panasinsene | 1626 | 1623 | Trace | - | Trace | - | Trace | - | [24] |
Alpha eudesmol | 1635 | 1632 | 5.34 | 0.87 | 2.31 | 0.74 | 3.83 | 1.81 | [24] |
Hinesol | 1644 | 1641 | Trace | - | 0.53 | 0.07 | 0.26 | 0.29 | [24] |
Selina-3,11-dien-6-a-ol | 1650 | 1644 | Trace | - | 5.30 | 0.81 | 2.65 | 2.95 | [24] |
Hydrocarbon monoterpenes | 4.93 | 7.18 | 6.06 | ||||||
Oxygenated monoterpenes | 53.62 | 59.67 | 56.64 | ||||||
Hydrocarbon sesquiterpenes | 7.14 | 6.13 | 6.64 | ||||||
Oxygenated sesquiterpenes | 23.77 | 7.50 | 15.64 | ||||||
Unidentified | 2.05 | 1.68 | 1.87 | ||||||
Others | 2.46 | 7.74 | 5.10 | ||||||
TOTAL | 93.98 | 89.91 | 91.94 |
* LRI: Lineal Retention Index.