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. 2018 Apr 12;23(4):896. doi: 10.3390/molecules23040896
ADMET acyclic diene metathesis polymerization
BD 1,3-butadiene
BMP 2,6-bis(1S,2S,5R)-(−)-menthoxypyridinyl
BSA bis(trimethylsilyl) acetamide
Cat. catalyst
CHP cumylhydroperoxide
COD 1,5-cyclooctadiene
Conf. configuration
Conv. conversion
CM cross metathesis
Cp cyclopentadiene
CPPA cis-1-propenylphosphonic acid
c.y. chemical yield
DMAP dimethylamino pyridine
DME 1,2-dimethoxyethane
DMF dimethylformamide
DS dodecylsulphate (OSO3C12H25)
EASC ethylaluminum sesquichloride
EDA ethyldiazoacetate
ee enantiomeric excess
equiv. equivalent
er enantiomeric ratio
FG functional group
GLC gas-liquid chromatography
Gr1 benzylidene-dichloro[bis(tricyclohexylphosphine)]ruthenium (Grubbs 1)
Gr2 benzylidene-dichloro(tricyclohexylphosphine)[(1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidenene]ruthenium (Grubbs 2)
HCC homogeneous chiral catalyst
Hex hexane
Lig ligand
Ln lanthanide
MAO methylalumoxane
n.d. not determined
NHC N-heterocyclic carbene
OTf triflate (trifluoromethanesulfonate)
PCy3 tricyclohexylphosphine
PMBOH p-methoxybenzyl alcohol
PMP 1,2,2,6,6-pentamethylpiperidine
py pyridine
Quant. quantitative
RCM ring-closing metathesis
RE rare earth
ROCM ring-opening cross metathesis
ROM ring-opening metathesis
ROMP ing-opening metathesis polymerization
r.t. room temperature
SIMes N,N’-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene
TBDMS tertiary butyldimethylsilyl group
TBHP tertiary butylhydroperoxide
TBS tertiary butyldimethylsilyl
Temp. temperature
TLC thin-layer chromatography
Tol. toluene
tol tolyl
TON turnover number