. 2016 Jun 15;7(9):6083–6098. doi: 10.1039/c6sc00462h

Table 3. Electrochemical data of selected complexes.

	E _pa ^a (V)	E red 1/2 ^a (V)	E _0–0 ^b (eV)	E(M*/M^–1) (V)	E(M⁺/M*) (V)
Pd-N-1	0.53	–2.47	2.48	0.01	–1.95
Pd-B-1	0.81	–2.54	2.71	0.17	–1.90
Pd-B-2	0.73	–2.44	2.70	0.26	–1.97
Pd-G-1	0.53	–2.24	2.61	0.37	–2.08

^aDetermined in DMF at 298 K with 0.1 mol dm^{–3 n}Bu₄NPF₆ as the supporting electrolyte. Scan rate: 100 mV s^–1. Values are versus Cp₂Fe^+/0. Cp₂Fe^+/0 occur at 0.06–0.08 V versus Ag/AgNO₃ (0.1 mol dm^–3 in CH₃CN) reference electrode.

^bEstimated from λ_max of the triplet emission band at 77 K.