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. 2018 Jun 10;140(25):7810–7819. doi: 10.1021/jacs.8b02388

Table 1. Values of ΔG° and m for the Cooperative and Isodesmic Pathways, Obtained from the Global Fitting of UV and CD Data for the Various Concentrations of (S)-1.

  1 μM 10 μM 100 μM
ΔG°coop (kJ/mol) –46 –45 –33
mcoop (kJ/mol) 194 101 67
σa 7.3 × 10–3 2.3 × 10–3 6.7 × 10–4
Δiso (kJ/mol) –40 –41 –31
miso (kJ/mol) 91 56 41
a

The cooperativity parameter σ is determined at 293 K.28