Figure 5.

Overlay of experimental (black lines) and simulated (red dashed lines) CV data (I = 0.2 M [Bu₄N][PF₆] in THF at room temperature, ν = 0.1 V·s^–1) for 1 at different concentrations (top) and with various amounts of Cl^– ions (bottom). Simulations according to the mechanism in Scheme 5 with the thermodynamic and kinetic parameters given in Table 1.