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. 2018 Jun 1;140(25):7922–7935. doi: 10.1021/jacs.8b03755

Table 2. Estimated Ranges for Rate and Equilibrium Constants of the Best Model for Electrochemical Reduction of 1 under N2 Atmospherea.

Parameter Range Value
K3 (M–1) 5 × 103–5 × 104 (1 × 104)
k3 (M–1 s–1) >5 × 107 (5 × 109)
K4 (M) 2 × 10–2–2 × 10–3 (5 × 10–3)
k4 (s–1) >5 × 102 (1 × 105)
k5 (M–1 s–1) 4 × 103–1 × 104 (7 × 103)
E3 (V) –1.84 to −1.88 (−1.86 V)
a

The values in parentheses were used to plot the simulation in Figures 8 and Figures S50–S53.