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. 2018 Jun 19;8(2):34. doi: 10.3390/membranes8020034
az geometric ratio L/R1
cp specific heat [J/molK] or [J/kgK]
d characteristic dimension of packed bed particles m
Drr radial dispersion coefficient m2/s
Dzz axial dispersion coefficient m2/s
D diffusion coefficient m2/s
D effective dispersion tensor m2/s
f average molar weight [kg/mol]
Jhm hydrogen mass flux through the membrane [kgH2/m2·s]
Jhm hydrogen molar flux through the membrane [molH2/m2·s]
k reaction rate constant [mol/m3·s·Pa]
ke effective heat conductivity [W/mK]
Keq equilibrium constant [Pa2]
L reactor length [m]
n unit vector normal to the membrane surface
P pressure [Pa]
Pi partial pressure of the i-th component [Pa]
PL outlet pressure Pa
PU reference pressure μUR1/κ Pa
Pm membrane permeability [kgH2/m2·s·Pa0.5]
Q˙wall heat flux between catalyst and reactor wall [W/m2]
Q˙permeate heat flux between catalyst and permeate [W/m2]
r radial coordinate [m]
ri volume-specific mass rate of production of the i-th component [kg/m3·s·Pa]
R gas constant [J/mol·K]
R1 inner reactor radius [m]
R2 outer reactor radius [m]
Rm volume-specific molar rate of methane consumption [mol/m3·s·Pa]
T temperature [K]
U inlet gas velocity m/s
Um heat transfer coefficient between permeate and retentate [W/m2K]
Uw heat transfer coefficient between wall and retentate [W/m2K]
v mass average velocity m/s
v molar average velocity m/s
Wi molar weight of the i-th component [kg/mol]
z axial coordinate [m]
Greek symbols
α dimensionless outlet pressure PL/PU
β ratio between characteristic and inlet velocities κPatm/μR1U
γ dimensionless permeability parameter PmRTPatm1/2/WhU
Γ 2γ/ar21
δ membrane thickness [m]
η proximity to reaction equilibrium
κ packed bed permeability m2
μ gas viscosity Pa·s
ΠH2 dimensionless permeate flow rate
ρ gas density kg/m3
ρi density of the i-th component kg/m3
σ geometric ratio, R2/R1
τ packed bed tortuosity factor
νi stoichiometric coefficient of the i-th component
Φ intrinsic membrane permeability
ωi mass fraction of the i-th component
Ω linear combination of hydrogen and methane densities νmρ˜h+νhρ˜m
Ψ hydrogen recovery (permeated hydrogen/produced hydrogen)
Ψs separator-base yield (permeated hydrogen/inlet hydrogen)
Θ inhibition factor
Dimensionless parameters
Da Damkholer number RTkR1/U
Da modified Damkholer number Da/Γ
D˜rr dimensionless radial dispersion Drr/D
D˜ dimensionless dispersion tensor D/D
lp characteristic length of permeation 2ρh0/Γ
Pe Peclet number UR1/D
Pem molecular Peclet number Ud/D
Pereff effective radial Peclet number Ud/Drr
Pezeff effective axial Peclet number Ud/Dzz
Re Reynolds number ρUR1/μ
Sc Schmidt number μ/ρD
Subscripts
c carbon dioxide
h hydrogen
m methane
w water
i i-th component