Table 2.

eATRP of BA in Miniemulsion with Different Surfactants and Catalysts, T = 65 °C^a

entry	aq. phase ligand	org. phase ligand	surfactant	Eapp	t (h)	Qb(C)	conv (%)	k papp c (h−1)	Mn	Mn,th	Đ
1	TPMA	-	Brij 98	Epc − 0.03 V	7.5	16.2	90	0.60	27800	3200	4.77
2	TPMA	-	SDS	Epc − 0.03 V	7.5	3.9	75	0.18	28400	27300	1.18
3	TPMA	BPMODA*	SDS	Epc	24	6.6	13	0.01	12400	5100	1.32
4d	BPMEA	BPMODA*	SDS	Epc	24	5.8	61	0.04	31800	22700	1.25
5	TPMA*2	-	SDS	Epc − 0.03 V	7.5	3.3	38	0.07	15900	14100	1.32
6	Me6TREN	-	SDS	Epc − 0.03 V	1.5	7.3	93	0.40	59500	33800	1.94
7	Me6TREN	-	SDS	Epc + 0.12 V	5	4.6	77	0.55	38700	27900	1.56
8d	BPMEA	-	SDS	Epc	24	2.0	66	0.06	29100	24300	4.62

^aConditions as in Table 1 unless otherwise stated.

^bCharge passed, determined from the chronoamperometry recorded during electrolysis (e.g. Figure S2).

^cThe slope of the ln([M]₀/[M]) vs time plot.

^dFrom reference ⁶.