. Author manuscript; available in PMC: 2018 Jul 3.

Published in final edited form as: Macromolecules. 2017 Apr 25;50(9):3726–2732. doi: 10.1021/acs.macromol.7b00530

Table 4.

eATRP of BA in Miniemulsion at Different Copper Concentrations and Degree of Polymerization^a

	[M]/[EBiB]/[Cu^IIBr₂]	Q^b (C)	Conv (%)	k_p^app ^c (h⁻¹)	M_n	M_n,th	Đ	d_v,final^d (nm)
1	280/1/0.09	2.6	60	0.14	24600	21800	1.19	105±1
2	280/1/0.20	3.9	75	0.18	28400	27300	1.18	126±2
3	280/1/0.34	4.8	87	0.27	33700	31900	1.16	174±1
4	100/1/0.07	4.9	80	0.22	10700	10600	1.26	117±1
5	500/1/0.36	1.8	47	0.09	31600	30200	1.09	100±1

Conditions as in Table 1 unless otherwise stated; E_app = E_pc − 0.03 V, selected from CV response; reaction time = 7.5 h.

Charge passed, determined from the chronoamperometry recorded during electrolysis (e.g. Figure S9).

The slope of the ln([M]₀/[M]) vs time plot.

Final average particle diameter, calculated from volume, determined by dynamic light scattering (DLS).