Table 5.
Fraction of Br-CuIIL+ Bound to SDS Interfaces in Micellar Systems or in Miniemulsions, T = 65 °C.
catalyst | environment | fbound |
---|---|---|
Br-CuIITPMA+ | micellesa | 0.79 |
Br-CuIITPMA+ | miniemulsionb | 0.95 |
Br-CuIIMe6TREN+ | miniemulsionb | <0.50 |
Br-CuIIBPMEA+ | miniemulsionb | 0.64 |
Water + 0.1 M NaBr + 10−3 M CuIIBr2/TPMA + 0.028 M SDS.
Cn-BuA/CNaBr/CCuIIBr2/CL= 280/20/0.2/0.4, 20% v/v BA in water, SDS = 28 mM = 4.6 wt % relative to BA, HD = 10.8 wt % relative to BA.