Table 6.

Molecular Description of the Br-Cu^IITPMA⁺/SDS System in a Single Miniemulsion Droplet^a

species	concentration (M)b	Nc	ratiod
SDSe	-	9.2×104	1.5×103
Hexadecane	-	2.7×105	4.4×103
Br-CuIITPMA+bound	-	3.0×103	48
[Br-CuIITPMA+/DS−]	9.9×10−5	62	1
BA	7.0	4.4×106	7.1×105
EBiB	2.5×10−2	1.6×104	2.6×102
Pn• f	0/11.7×10−6 (1.3×10−9)	0/1 (8.2×10−4)	0/2.9×10−2 (2.3×10−5)

^aConditions as in Table 1.

^bConcentration of the species in the organic phase (V = 8 mL).

^cAverage number of particles of each species in a single droplet.

^dN/N_catalyst.

^eThe surfactant available to stabilize the droplets was considered as C_SDS – cmc (critical micellar concentration, see SI).

^fTwo different values are reported, considering that during polymerization in most droplets the concentration of radical is either 0 or 1. In parentheses the average of the whole organic phase.