Skip to main content
. 2017 Aug 16;10(17):3435–3444. doi: 10.1002/cssc.201701120

Table 1.

Continuous hybrid processes comprising of flow reactors and nanofiltration.

Reference Role of membrane Membrane Reaction Reactor Solvent Catalyst
2a Catalyst retention and solvent exchange PEEK and Duramem 150 Heck coupling PFR‐m‐CSTR DMF→EtOH Pd complex[a]
9f Catalyst removal Inopor TiO2 Suzuki coupling Coil reactor EtOH, iPrOH Pd complex[a]
14 Catalyst recycling PEEK Asymmetric hydrogenation PBR Toluene, tBuOH Ru complex[a]
15 Catalyst retention PEEK Heck coupling PFR‐m‐CSTR DMF Pd complex[a]
This work Solvent and reagent recycling Duramem 150 Michael Addition PBR Acetone Trialkylamine base[b]

[a] Homogeneous. [b] Heterogeneous. PEEK: polyether ether ketone; PFR: plug flow reactor; CSTR: continuous stirred‐tank reactor; PBR: packed bed reactor; ‐m‐ refers to well‐mixed DMF: N,N‐dimethylformamide.