Table 1.
Reference | Role of membrane | Membrane | Reaction | Reactor | Solvent | Catalyst |
---|---|---|---|---|---|---|
2a | Catalyst retention and solvent exchange | PEEK and Duramem 150 | Heck coupling | PFR‐m‐CSTR | DMF→EtOH | Pd complex[a] |
9f | Catalyst removal | Inopor TiO2 | Suzuki coupling | Coil reactor | EtOH, iPrOH | Pd complex[a] |
14 | Catalyst recycling | PEEK | Asymmetric hydrogenation | PBR | Toluene, tBuOH | Ru complex[a] |
15 | Catalyst retention | PEEK | Heck coupling | PFR‐m‐CSTR | DMF | Pd complex[a] |
This work | Solvent and reagent recycling | Duramem 150 | Michael Addition | PBR | Acetone | Trialkylamine base[b] |
[a] Homogeneous. [b] Heterogeneous. PEEK: polyether ether ketone; PFR: plug flow reactor; CSTR: continuous stirred‐tank reactor; PBR: packed bed reactor; ‐m‐ refers to well‐mixed DMF: N,N‐dimethylformamide.