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Reductive C−C bond formations using substrates 1 a‐Br–1 b‐Br. Reaction conditions: 300 μL stock solution (10 mm substrate, 1 vol% DMF, 1,2‐DME as internal standard, and 15 mm NADH in 50 mm sodium phosphate‐buffer at pH 7.5 and 150 mm NaCl) and enzyme (5 μm) in 300 μL sodium phosphate‐buffer (50 mm, pH 7.5, 150 mm NaCl) per tube, 180 min and 25 °C at 300 rpm. DMF=N,N‐dimethylformamide, 1,2‐DME=1,2‐dimetheoxyethane.
