| Crystal data |
| Chemical formula |
Rh6Mn5Bi18
|
RhMnBi3
|
|
M
r
|
4653.80 |
784.79 |
| Crystal system, space group |
Tetragonal, P42/m
n
m
|
Orthorhombic, C
m
m
m
|
| Temperature (K) |
293 |
293 |
|
a, b, c (Å) |
18.526 (3), 18.526 (3), 4.1722 (11) |
8.885 (3), 13.696 (6), 4.1310 (12) |
| α, β, γ (°) |
90, 90, 90 |
90, 90, 90 |
|
V (Å3) |
1432.0 (6) |
502.7 (3) |
|
Z
|
2 |
4 |
| Radiation type |
Mo Kα |
Mo Kα |
| μ (mm−1) |
115.57 |
110.13 |
| Crystal size (mm) |
0.16 × 0.03 × 0.02 |
0.10 × 0.05 × 0.03 |
| |
| Data collection |
| Diffractometer |
Nonius KappaCCD |
Nonius KappaCCD |
| Absorption correction |
Multi-scan (SCALEPACK; Otwinowski & Minor, 1997 ▸) |
Multi-scan (SCALEPACK; Otwinowski & Minor, 1997 ▸) |
|
T
min, T
max
|
0.009, 0.011 |
0.003, 0.005 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
21380, 1784, 1297 |
3699, 667, 522 |
|
R
int
|
0.169 |
0.141 |
| (sin θ/λ)max (Å−1) |
0.803 |
0.806 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.044, 0.088, 1.05 |
0.094, 0.257, 1.19 |
| No. of reflections |
1784 |
667 |
| No. of parameters |
50 |
21 |
| Δρmax, Δρmin (e Å−3) |
4.24, −3.66 |
11.68, −8.87 |
