Table 3.
Parameters of the original TIP3P and Bind3P water models, and a comparison of bulk properties computed with both. The geometry of the water model and its partial charges are unchanged in Bind3P.
| Expt. | TIP3P | Bind3P | |
|---|---|---|---|
| σow (Å) | - | 3.1508 | 3.1319 |
| εow (kcal/mol) | - | 0.1520 | 0.1818 |
| q (e) | - | 0.417 | 0.417 |
| Density (g/cm3) | 0.997[57] | 0.985 (<0.001) | 0.990 (<0.001) |
| Static dielectric constant | 78.5[58] | 98 (2) | 102 (4) |
| Isothermal compressibility (10−6 bar−1) | 45.8[59] | 58 (1) | 55 (2) |
| Coeff. of thermal expansion (10−4 K−1) | 2.0[59] | 9.1 (0.4) | 9.5 (0.7) |
| Heat of vaporization (kcal/mol) | 10.52[60] | 10.09 (0.01) | 10.02 (0.02) |
| Position of first RDF peak (Å) | 2.82[55] | 2.78 (<0.01) | 2.81 (0.01) |
| Height of first RDF peak | 2.49[55] | 2.71 (<0.01) | 2.64 (<0.01) |
All bulk properties were computed at 298.15 K and 1 atm and reported as the mean, with the standard deviation across triplicate calculations given in parentheses. The properties of the TIP3P water model listed in this table were also computed in the present work, and are in good agreement with those reported in ref61.