Table 1. NMR Data of Anomoian B (1) in CD3OD and Aplyzanzine B (2) in CDCl3.
1 |
2 |
||||
---|---|---|---|---|---|
pos. | δC type | δHm (J in Hz) | pos. | δC type | δHm (J in Hz) |
1 | 134.5 C | 1 | 133.4 C | ||
2 | 135.2 CH | 7.51s | 2 | 133.6 CH | 7.40s |
3 | 119.3 C | 3 | 118.5 C | ||
4 | 155.1 C | 4 | 153.9 C | ||
5 | 119.3 C | 5 | 118.5 C | ||
6 | 135.2 CH | 7.51s | 6 | 133.6 CH | 7.40s |
7 | 34.3 CH2 | 3.36m | 7 | 34.1 CH2 | 3.22dd (12.4, 3.6) |
3.00m | 3.09dd (12.4, 11.3) | ||||
8 | 70.5 CH | 3.91dd (11.2, 4.6) | 8 | 60.4 CH | 4.97dd (11.3, 3.6) |
9 | 167.2 C | 9 | 166.8 C | ||
10 | 38.0 CH2 | 3.51m | 10 | 54.9 CH2 | 5.06d (17.5) |
3.28m | 4.19d (17.5) | ||||
11 | 30.6 CH2 | 1.84m | 11 | 189.3 C | |
1.70m | 12 | 132.5 C | |||
12 | 71.6 CH2 | 3.87m | 13 | 132.7 CH | 8.03s |
3.75m | 14 | 118.9 C | |||
13 | 153.4 C | 15 | 157.0 C | ||
14 | 119.4 C | 16 | 118.9 C | ||
15 | 134.4 CH | 7.57s | 17 | 132.7 CH | 8.03s |
16 | 135.1 C | 18 | 69.9 CH2 | 4.13t (5.5) | |
17 | 134.4 CH | 7.57s | 19 | 25.3 CH2 | 2.32dq (11.2, 5.5) |
18 | 119.4 C | 20 | 55.5 CH2 | 3.42m | |
19 | 30.3 CH2 | 2.99m | 21 | 40.0 CH3 | 2.97s |
20 | 59.1 CH2 | 3.33m | 22 | 40.0 CH3 | 2.97s |
21 | 42.5 CH3 | 2.99s | 23 | 42.9 CH3 | 2.88s |
22 | 42.5 CH3 | 2.99s | 24 | 42.9 CH3 | 2.88s |
23 | 43.6 CH3 | 2.93s | 25 | 60.7 CH3 | 3.85s |
24 | 43.6 CH3 | 2.93s | 26 | 37.6 CH3 | 2.75s |
25 | 61.1 CH3 | 3.77s |