Table 3b. Decay Characteristic of Solvent Response Function, C(t), of C-480 in the Presence of Pure 12-4(OH)-12 and 12-4(OH)-12 at Various Concentrations of Urea.
| urea (M) | a1s | τ1s (ps) | a2s | τ2s (ps) | ⟨τs⟩ (ps) | Δν (cm–1) |
|---|---|---|---|---|---|---|
| 0.0 | 0.68 ± 0.01 | 355.43 ± 0.01 | 0.28 ± 0.01 | 1861.01 ± 0.08 | 762.76 | 1910 |
| 0.5 | 0.56 ± 0.04 | 297.45 ± 0.01 | 0.44 ± 0.04 | 1409.21 ± 0.25 | 786.62 | 1930 |
| 1.0 | 0.66 ± 0.02 | 347.02 ± 0.01 | 0.34 ± 0.02 | 1735.24 ± 0.17 | 819.01 | 2057 |
| 2.0 | 0.52 ± 0.03 | 337.47 ± 0.02 | 0.48 ± 0.03 | 1498.59 ± 0.13 | 894.81 | 1954 |
| 3.0 | 0.73 ± 0.02 | 371.56 ± 0.01 | 0.27 ± 0.02 | 1768.15 ± 0.16 | 748.64 | 1911 |
| 4.0 | 0.51 ± 0.01 | 262.44 ± 0.01 | 0.49 ± 0.01 | 1230.69 ± 0.02 | 736.88 | 2098 |
| 5.0 | 0.67 ± 0.01 | 175.85 ± 0.01 | 0.33 ± 0.01 | 1350.64 ± 0.03 | 563.53 | 2366 |
Δν = ν(0) – ν(∞).