Table 3c. Decay Characteristic of Solvent Response Function, C(t), of C-480 in the Presence of Pure 12-4(OH)2-12 and 12-4(OH)2-12 at Various Concentrations of Ureaa.
| urea (M) | a1s | τ1s (ps) | a2s | τ2s (ps) | ⟨τs⟩ (ps) | Δν (cm–1) |
|---|---|---|---|---|---|---|
| 0.0 | 0.80 ± 0.04 | 493.77 ± 0.02 | 0.20 ± 0.03 | 2589.21 ± 0.61 | 912.86 | 2075 |
| 0.5 | 0.82 ± 0.03 | 521.95 ± 0.02 | 0.18 ± 0.03 | 2847.76 ± 0.69 | 940.60 | 2050 |
| 1.0 | 0.82 ± 0.04 | 535.06 ± 0.02 | 0.18 ± 0.03 | 2930.32 ± 0.71 | 966.21 | 2030 |
| 2.0 | 0.86 ± 0.03 | 515.85 ± 0.03 | 0.14 ± 0.02 | 4721.38 ± 0.73 | 1104.62 | 1997 |
| 3.0 | 0.70 ± 0.02 | 391.78 ± 0.01 | 0.30 ± 0.02 | 1743.48 ± 0.11 | 797.29 | 1930 |
| 4.0 | 0.68 ± 0.02 | 392.63 ± 0.01 | 0.32 ± 0.02 | 1580.51 ± 0.07 | 772.75 | 1885 |
| 5.0 | 0.75 ± 0.02 | 376.72 ± 0.01 | 0.25 ± 0.02 | 1867.86 ± 0.13 | 749.51 | 1820 |
Δν = ν(0) – ν(∞).