Table 5c. Rotational Relaxation Parameters of C-480 in the Micelles of Gemini-C and Urea Mixed Systemsa.
| urea (M) | r0 | a1r | τ1r (ns) | a2r | τ2r (ns) | ⟨τr⟩ (ns) |
|---|---|---|---|---|---|---|
| 0.0 | 0.30 ± 0.04 | 0.85 ± 0.01 | 0.76 ± 0.08 | 0.15 ± 0.02 | 12.82 ± 0.97 | 2.57 |
| 0.5 | 0.28 ± 0.03 | 0.86 ± 0.02 | 0.75 ± 0.08 | 0.14 ± 0.01 | 12.38 ± 0.89 | 2.38 |
| 1.0 | 0.28 ± 0.03 | 0.90 ± 0.02 | 0.79 ± 0.08 | 0.10 ± 0.01 | 12.68 ± 0.98 | 1.98 |
| 2.0 | 0.27 ± 0.03 | 0.91 ± 0.01 | 0.78 ± 0.08 | 0.09 ± 0.01 | 13.25 ± 0.99 | 1.90 |
| 3.0 | 0.27 ± 0.03 | 0.87 ± 0.02 | 0.73 ± 0.07 | 0.13 ± 0.01 | 7.19 ± 0.59 | 1.57 |
| 4.0 | 0.26 ± 0.03 | 0.89 ± 0.02 | 0.72 ± 0.07 | 0.11 ± 0.01 | 7.84 ± 0.63 | 1.50 |
| 5.0 | 0.26 ± 0.03 | 0.57 ± 0.02 | 0.39 ± 0.05 | 0.43 ± 0.02 | 1.89 ± 0.12 | 1.04 |
λex = 375 nm, λem = 470 nm.