Table 6c. Hydrodynamic Diameter, Time for Overall Rotational Motion of the Micelle (τm), Lateral Diffusion Time (τD), Wobbling Motion Time (τw), Wobbling Diffusion Coefficient (Dw), Cone Angle (θo), and Order Parameter (|S|) Obtained from the Anisotropy Decays of C-480 in the Micelles of Gemini-C and Urea.
| Gemini-C + urea | hydrodynamic diameter (nm) | τw (ns) | τm (ns) | τD (ns) | Dw × 10–8 (s–1) | θo (deg) | |S| | θo (deg)a |
|---|---|---|---|---|---|---|---|---|
| 0.0 | 1.28 ± 0.05 | 0.81 ± 0.08 | 237.79 ± 0.97 | 13.55 ± 0.97 | 3.82 ± 0.56 | 59.0 ± 0.8 | 0.39 ± 0.02 | 62.0 ± 0.9 |
| 0.5 | 1.28 ± 0.05 | 0.79 ± 0.08 | 237.79 ± 0.89 | 13.06 ± 0.89 | 4.09 ± 0.59 | 60.3 ± 0.8 | 0.37 ± 0.02 | 59.3 ± 0.9 |
| 1.0 | 1.15 ± 0.02 | 0.84 ± 0.08 | 172.45 ± 0.98 | 13.69 ± 0.98 | 4.29 ± 0.51 | 63.7 ± 0.7 | 0.32 ± 0.01 | 53.1 ± 0.7 |
| 2.0 | 1.22 ± 0.04 | 0.83 ± 0.08 | 205.89 ± 0.99 | 14.16 ± 0.99 | 4.53 ± 0.64 | 65.0 ± 0.6 | 0.30 ± 0.02 | 50.8 ± 0.8 |
| 3.0 | 0.88 ± 0.02 | 0.81 ± 0.07 | 77.27 ± 0.59 | 7.93 ± 0.59 | 4.08 ± 0.45 | 61.0 ± 0.7 | 0.36 ± 0.01 | 58.1 ± 0.7 |
| 4.0 | 1.05 ± 0.03 | 0.79 ± 0.07 | 131.26 ± 0.63 | 8.34 ± 0.63 | 4.46 ± 0.59 | 63.0 ± 0.8 | 0.33 ± 0.02 | 54.3 ± 0.8 |
| 5.0 | 1.34 ± 0.06 | 0.49 ± 0.05 | 272.82 ± 0.12 | 1.91 ± 0.12 | 3.07 ± 0.29 | 41.1 ± 0.6 | 0.66 ± 0.01 |
θo is calculated using the spinning-in-equatorial-band model.