Table 2. PF-BTB Infrared Bands Assignmenta.
experimental bands (cm–1) | literature data17,21 (cm–1) | assignment |
---|---|---|
3049 | 3047 | νC–H aromatic OP |
3006 | 3024 | νC–H trans-vinyl OP |
2922 | 2920 | νaliphatic |
2849 | 2852 | νaliphatic |
1690 | 1679 | νC=N (benzothiadiazole) |
1602 | 1594 | νC=C aromatic |
1534 | 1561 | νC=C aromatic |
1463 | 1423 | νC=C aromatic |
1096 | 1108 | δC–H aromatic IP |
963 | 965 | δC–H trans-vinyl IP |
802 | 837 | δC–H aromatic OP |
747 | 784 | unknown |
IP = in-plane, OP = out-of-plane.