Table 1. Stern–Volmer Constants and Thermodynamic Parameters for Cur-AgNPs.
temperature (K) | KSV (104 M–1) | kq (×1013 M–1 s–1) | K (×103 M–1) | ΔG° (kJ mol–1) | ΔH° (kJ mol–1) | ΔS° (J mol–1 K–1) |
---|---|---|---|---|---|---|
293 | 33.49 | 3.35 | 4.80 | –54.02 | 81.75 | 184.63 |
303 | 40.03 | 4.00 | 3.13 | –17.80 | 44.29 | 58.89 |
313 | 35.91 | 3.59 | 1.38 | 17.22 | 9.22 | –54.99 |
323 | 30.64 | 3.06 | 0.43 | 51.16 | –23.67 | –158.45 |
333 | 24.92 | 2.49 | 0.11 | 84.11 | –54.59 | –252.74 |