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. 2018 Jun 19;9(26):5837–5841. doi: 10.1039/c8sc01682h

Table 3. Selected bond distances in Å for [AsCl(BIMEt3)][OTf]2 [SbF(BIMEt3)][OTf]2 [As(BIMEt3)][OTf]3 and [Sb(BIMEt3)][OTf]3.

[AsCl(BIMEt3)]3+ [As(BIMEt3)]3+ [SbF(BIMEt3)]2+ [Sb(BIMEt3)]3+
Pn–N2 1.964(2) 1.918(4) 2.214(2) 2.193(2) 2.168(2)
2.078(2) 2.085(4) 2.165(3) 2.233(2) 2.246(2)
2.251(2) 2.195(4) 2.335(2) 2.346(2)
Pn–N1 2.268(2) 2.104(4) 2.635(3) 2.389(2) 2.370(2)
Pn–OTf 2.646(4) 2.551(2) 2.421(2) 2.485(2)
2.796(4) 2.793(2) 3.181(2) 3.171(2)
2.833(2) 2.820(2)
3.258(2) 3.313(2)
Pn–X 2.3342(7) 3.913(2) X = Cl 1.9344(19) X = F