Table 3. Selected bond distances in Å for [AsCl(BIMEt3)][OTf]2 [SbF(BIMEt3)][OTf]2 [As(BIMEt3)][OTf]3 and [Sb(BIMEt3)][OTf]3.
[AsCl(BIMEt3)]3+ | [As(BIMEt3)]3+ | [SbF(BIMEt3)]2+ | [Sb(BIMEt3)]3+ |
||
Pn–N2 | 1.964(2) | 1.918(4) | 2.214(2) | 2.193(2) | 2.168(2) |
2.078(2) | 2.085(4) | 2.165(3) | 2.233(2) | 2.246(2) | |
2.251(2) | 2.195(4) | 2.335(2) | 2.346(2) | ||
Pn–N1 | 2.268(2) | 2.104(4) | 2.635(3) | 2.389(2) | 2.370(2) |
Pn–OTf | — | 2.646(4) | 2.551(2) | 2.421(2) | 2.485(2) |
2.796(4) | 2.793(2) | 3.181(2) | 3.171(2) | ||
2.833(2) | 2.820(2) | ||||
3.258(2) | 3.313(2) | ||||
Pn–X | 2.3342(7) 3.913(2) X = Cl | 1.9344(19) X = F |