Table 1. Crystallographic bond metrics for the Fe complexes with comparative examples ^a .

MR	1H	1NO2	2a	2b	K[LiPrFeIIIOH] b	{K[LdmpFeNO]}7 c
Fe–Namine (Å)	2.235(2)	2.231(1)	2.251(2)	2.245(2)	2.194(3)	2.198(2)
Fe–Namidate ave (Å)	2.015	2.158	2.114	2.027	2.022	2.026
Ccarbonyl–Nimidate	—	—	1.304(4)	1.295(4)	—	—
Ccarbonyl–Namidate	1.338(3)	1.355(2)	1.339(4)	1.349(4)	1.307(6)	1.339(3)
	1.339(3)	1.324(2)	1.341(3)	1.350(4)	1.314(5)	1.339(3)
	1.331(2)	1.335(2)	—	—	1.321(4)	1.341(3)
Fe–Oimidate	—	—	2.071(2)	1.977(2)	—	—
Fe–X (Å)	2.046(1) (X = OAc)	2.111(1) (X = OAc)	1.800 (X = O)	1.782(1) (X = O)	1.876(3) (X = OH)	1.748(2) (X = NO)
Fe–O–Fe (°)	—	—	128.1	180	—	—

^aCounterion is Me₄N⁺ unless otherwise noted.

^bShorter C–N bond lengths due to aliphatic trisacetamidate ligand L^iPr.23

^cFrom ref. 25.