Table 6.
Solvent dynamics of cyclohexane around each α-helix.
| α1 (Ext) | α2 (Int-Ext) | α3 (Int-Ext) | α4 (Int) | α5 (Ext) | α6 (Int) | α7 (Int-Ext) | α8 (Ext) | α9 (Int-Ext) | α10 (Ext) | |
|---|---|---|---|---|---|---|---|---|---|---|
| Diffusion coefficient (10−5 cm2/s) | 0.76 ± 0.02 | 0.67 ± 0.02 | 0.67 ± 0.02 | 0.64 ± 0.02 | 0.95 ± 0.02 | 0.65 ± 0.02 | 0.74 ± 0.01 | 0.78 ± 0.02 | 0.64 ± 0.01 | 1.04 ± 0.01 |
| Residence time (ps) | 24.1 ± 1.0 | 29.4 ± 0.9 | 28.5 ± 0.9 | 38.6 ± 0.9 | 20.8 ± 1.0 | 39.2 ± 1.2 | 24.1 ± 0.6 | 23.8 ± 0.3 | 32.9 ± 0.5 | 15.8 ± 0.4 |
(Calculated diffusion coefficient for the bulk solvent = 1.05 × 10−5 cm2/s).