Table 1.

Exploration of the substrate scope of the palladium‐catalyzed N‐arylation of tertiary =NH sulfonimidamide 2 aa: Variation of aryl bromide 8.

Aryl bromide (R4Br)	Isolated yield [%]
8 a: bromobenzene	2 ba: 86
8 b: 1‐bromo‐2‐fluorobenzene	2 bb: 46
8 c: 1‐bromo‐3‐fluorobenzene	2 bc: 97
8 d: 1‐bromo‐4‐fluorobenzene	2 bd: 72
8 e: 2‐bromotoluene	2 be: 97
8 f: 3‐bromotoluene	2 bf: 84
8 g: 4‐bromotoluene	2 bg: 99
8 h: 2‐bromo‐1,3,5‐trimethylbenzene	2 bh: 3
8 i: 3‐bromoanisole	2 bi: 65
8 j: 4‐bromobenzonitrile	2 bj: 88
8 k: methyl 4‐bromobenzoate	2 bk: 99
8 l: 4‐bromobenzotrifluoride	2 bl: quant.
8 m: 2‐bromopyridine	2 bm: 71
8 n: 3‐bromopyridine	2 bn: 77
8 o: 4‐bromopyridine	2 bo: 72
8 p: 2‐bromopyrimidine	2 bp: 77
8 q: 2‐bromo‐1,3‐thiazole	2 bq: 45