Table 2.

Exploration of the substrate scope of the N‐alkylation of tertiary =NH sulfonimidamide 2 aa: Variation of alkyl halide 9.

Alkyl halide (R4Br/I)		Isolated yield [%]
9 a: bromoethane		2 ca: 99
9 b: 2‐bromopropane		2 cb: 38
9 c: (bromomethyl)cyclobutane		2 cc: 61
9 d: (bromomethyl)cyclopentane		2 cd: 29
9 e: (bromomethyl)cyclohexane		2 ce: 71
9 f: 4‐(bromomethyl)tetrahydro‐2H‐pyran		2 cf: 60
9 g:		2 cg: 35
9 h:		2 ch: 50
9 i:		2 ci: 46
9 j: 1‐bromo‐2‐methoxyethane		2 cj: 80
9 k: ethyl bromoacetate		2 ck: 40
9 l:		2 cl: 13
9 m: methyl iodide		2 cm: 59
9 n: benzyl bromide		2 cn: 57
9 o:		2 co: 62
9 p: allyl bromide		2 cp: 72
9 q: propargyl bromide		2 cq: 63
9 r: 1‐bromobut‐2‐yne		2 cr: 71