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. 2018 Jun 19;24(37):9295–9304. doi: 10.1002/chem.201801557

Table 5.

N‐Aminocarbonylation of tertiary =NH sulfonimidamide 2 aa with isocyanates 12 af (urea formation).

graphic file with name CHEM-24-9295-g017.jpg
Isocyanate (R7N=C=O) Isolated yield [%]
12 a: n‐propyl isocyanate 2 ga: 65
12 b: phenyl isocyanate 2 gb: 79
12 c: 4‐nitrophenyl isocyanate 2 gc: 82
12 d: 2,5‐dimethoxyphenyl isocyanate 2 gd: 75
12 e: 4‐methoxyphenyl isocyanate 2 ge: 82
12 f: graphic file with name CHEM-24-9295-g018.jpg 2 gf: 49