Table 3.
Hydrogen bond lengths (Å) and bond angles (°) for complexes 1, 2, and 3.
D−H⋯A | d(D−H) | d(H−A) | d(D−A) | ∠(DHA) |
---|---|---|---|---|
Complex 1 | ||||
O4–H4⋯O2#1 | 0.82 | 1.79 | 2.609(4) | 173.4 |
C26–H26⋯O4 | 0.93 | 2.60 | 3.141(5) | 117.9 |
O(5′)–H(5A′)⋯O(2) | 0.82 | 2.15 | 3.175(5) | 136.8 |
O(5)–H(5A)⋯O(2) | 0.82 | 2.02 | 2.765(8) | 149.9 |
| ||||
Complex 2 | ||||
O4–H4⋯O2#1 | 0.82 | 1.76 | 2.576(4) | 170.4 |
C32–H32⋯O2#3 | 0.93 | 2.36 | 3.274(5) | 166.8 |
Complex 3 | ||||
| ||||
O(16)–H(16)⋯O(2) | 0.82 | 2.03 | 2.828(10) | 163.2 |
O(15)–H(15)⋯O(18)#4 | 0.82 | 1.83 | 2.640(10) | 171.2 |
O(5)–H(5)⋯O(7)#5 | 0.82 | 1.93 | 2.697(8) | 154.2 |
O(10)–H(10)⋯O(12)#5 | 0.82 | 1.78 | 2.588(8) | 169.9 |
O(17)–H(17)⋯O(2)#6 | 0.82 | 2.00 | 2.733(9) | 148.3 |
O(19)–H(19)⋯O(7)#6 | 0.82 | 2.03 | 2.853(9) | 177.6 |
O(18)–H(18)⋯O(11)#6 | 0.82 | 1.86 | 2.659(9) | 166.1 |
O(20)–H(20)⋯O(13)#7 | 0.82 | 2.06 | 2.884(12) | 179.0 |
O(20)–H(20)⋯O(14)#7 | 0.82 | 2.55 | 2.966(12) | 112.5 |
Symmetry codes for the complex: #1: 0.5−x, 0.5−y, and 1−z; #2: 2−x, −y, and 1−z; #3: 1−x, −y, and 1−z; #4: −x+1, −y + 1, and −z; #5: −x + 2, −y + 1, and −z + 1; #6: x−1, y, and z; #7: x, y, and z + 1.