Table 1.
1H NMR and 13C NMR data for compounds 1 and 7.
1a |
7b |
||||
---|---|---|---|---|---|
Position | δC | δH (J Hz) | Position | δC | δH (J Hz) |
1a | 43.8 | 1.12, m | 2 | 161.6 | |
1b | 1.18, m | 3 | 87.5 | 5.65, s | |
2a | 18.7 | 1.53, m | 4 | 169.1 | |
2b | 1.76, m | 5 | 149.2 | ||
3a | 38.3 | 1.20, m | 6 | 107.7 | 7.26, s |
3b | 1.69, m | 7 | 131.4 | ||
4 | 39.2 | 8 | 143.7 | ||
5 | 45.9 | 1.80, m | 9 | 132.1 | |
6 | 69.3 | 5.67, m | 10 | 105.9 | |
7a | 28.8 | 2.12, m | 11 | 65.4 | 4.67, d (6.5) |
7b | 2.47, m | 12 | 119.8 | 5.47, d (6.5) | |
8 | 37.0 | 2.87, t (8.0) | 13 | 137.3 | |
9 | 50.7 | 2.40, m | 14 | 18.1 | 1.74, s |
10 | 35.7 | 15 | 25.5 | 1.76, s | |
11a | 69.4 | 4.28,dd (5.5,10) | 16 | 61.2 | 4.80, d (4.0) |
11b | 4.47, d (9.5) | 17 | 56.7 | 3.94, s | |
12 | 181.2 | ||||
13 | 20.3 | 0.88, s | |||
14a | 71.2 | 3.03, d (6.5) | |||
14b | 3.56, d (6.0) | ||||
15 | 19.1 | 1.43, s | |||
1′ | 168.1 | ||||
2′ | 132.0 | ||||
3′ | 130.6 | 7.95,dd (1.5,7.0) | |||
4′ | 129.6 | 7.48, d (8.0) | |||
5′ | 134.1 | 7.60, t (7.5) | |||
6′ | 129.6 | 7.47, d (7.5) | |||
7′ | 130.6 | 7.97, dd (1.5,7.0) |
aRecorded in MeOD. brecorded in DMSO-d6.