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The first reaction of the pentose phosphate pathway is the enzymatic dehydrogenation of glucose 6-phosphate by glucose 6-phosphate dehydrogenase (G6PD).
ADP = adenosine diphosphate; ATP = adenosine triphosphate; eNOS = enzyme nitric oxide synthase; GSH = glutathione; GSSG = glutathione disulfide; NADP = nicotinamide adenine dinucleotide phosphate; NADP+ = reduced nicotinamide adenine dinucleotide phosphate; NO = nitric oxide
