Table 2.

151-MHz ¹³C NMR data for six mycotoxin glucosides in α and ß configuration recorded in d₄-methanol at 26 °C. Chemical shift assignment

13C-NMR shifts
Analyte
Position	T-2-3-O-α-Glcp	HT-2-3-O-α-Glcp	15-OH-T-2-3-O-α-Glcp	T-2-3-O-β-Glcp	HT-2-3-O-β-Glcp	T2 triol-3-O-β-Glcp
2	77.79	77.90	78.06	80.32	80.44	80.60
3	82.25	85.45	82.86	83.69	87.13	87.81
4	82.05	79.89	82.39	81.02	79.92	79.81
5	50.01	49.81	49.91	49.91	49.87	49.60
6	44.28	43.91	45.68	44.17	43.99	44.63
7	28.52	28.60	28.72	28.64	28.72	29.22
8	69.37	69.62	69.73	69.18	69.58	69.86
9	137.06	137.04	137.01	137.21	137.29	137.32
10	125.17	125.40	125.40	124.90	125.35	125.58
11	68.60	68.72	69.00	68.34	68.68	69.05
12	65.15	65.21	65.40	65.12	65.43	64.10
13	47.76	47.33	47.89	47.72	47.43	47.59
14	7.13	7.52	6.93	6.90	7.41	7.05
15	65.84	65.88	63.75	65.68	65.86	65.81
16	20.42	20.44	20.37	20.29	20.50	20.44
17	173.95	174.05	174.25	173.81	174.06	174.25
18	44.46	44.54	44.56	44.35	44.58	45.32
19	26.89	29.93	26.87	26.78	26.97	26.94
20	22.76	22.77	22.74	22.61	22.75	22.79
21	22.71	22.72	22.73	22.56	20.50	20.44
CH3 (Ac)	21.23 20.78	21.21	20.81	21.07	21.21
				20.65
C=O (Ac)	172.41	172.28	172.74	172.09	172.17
	172.09			172.02
1’	99.54	99.32	99.77	103.61	104.13	104.50
2’	73.37	73.55	73.55	74.63	74.89	75.01
3’	74.70	74.94	74.80	77.91	78.20	78.13
4’	71.45	71.77	71.51	71.29	71.36	71.31
5’	74.42	74.17	74.44	78.17	78.24	78.18
6’	62.22	62.57	62.20	62.47	62.58	62.52