Table 2.
Peak | Compound | LRI | Relative Quantity, % | ||
---|---|---|---|---|---|
DB-5MSa | DB-WAXb | Carvone (A) | Citral (B) | ||
1 | 6-Methyl-5-hepten-2-one | 986 | 1241 | – | 3.3 |
2 | β-Myrcene | 991 | 1064 | 0.8 | – |
3 | Limonene | 1034 | 1105 | 29.1 | 6.6 |
4 | trans-β-Ocimene | 1047 | 1153 | 0.7 | 0.2 |
5 | Linalool | 1100 | 1453 | 0.6 | 1.9 |
6 | Citronellal | 1154 | 1381 | – | 1.1 |
7 | Borneol | 1181 | 1613 | 0.8 | – |
8 | cis-Dihydrocarvone | 1203 | 1517 | 0.2 | – |
9 | trans-Dihydrocarvone | 1211 | 1537 | 0.2 | – |
10 | Nerol | 1231 | 1708 | – | 0.8 |
11 | Neral | 1248 | 1589 | – | 21.5 |
12 | Geraniol | 1252 | 1755 | – | 5.6 |
13 | Carvone | 1258 | 1653 | 35.0 | – |
14 | Piperitone | 1264 | 1641 | 2.4 | – |
15 | Geranial | 1275 | 1643 | – | 28.7 |
16 | Piperitenone | 1349 | 1842 | 4.0 | – |
17 | Geranyl Acetate | 1379 | 1662 | – | 1.5 |
18 | β-Bourboneno | 1396 | 1428 | 1.2 | – |
19 | β-Elemene | 1397 | 1496 | 1.0 | 3.0 |
20 | trans-β-Caryophyllene | 1436 | 1506 | 0.2 | 12.1 |
21 | β-Gurjunene | 1444 | 1447 | 0.2 | – |
22 | α-Guaiene | 1447 | 1498 | – | 1.8 |
23 | trans-β-Farnesene | 1456 | 1570 | 0.7 | – |
24 | α-Humulene | 1471 | 1580 | 0.1 | 2.7 |
25 | γ-Gurjunene | 1475 | 1587 | 0.4 | – |
26 | Germacrene D | 1486 | 1552 | 0.1 | 2.6 |
27 | Bicyclosesquiphellandrene | 1496 | 1624 | 8.2 | – |
28 | Bicyclogermacrene | 1509 | 1608 | 0.5 | – |
29 | α-Bulnesene | 1515 | 1627 | – | 1.4 |
30 | Cubebol | 1528 | 1855 | 0.5 | – |
31 | Germacrene-4-ol | 1591 | 1967 | 0.6 | – |
32 | Caryophyllene Oxide | 1600 | 1909 | – | 2.3 |
LRI Linear retention index
aLinear Retention Index experimentally determined in DB-5MS (60 m) column
bLinear Retention Index experimentally determined in DB-WAX (60 m) column