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. 2017 Mar 1;8(5):3529–3537. doi: 10.1039/c7sc00117g

Table 1. Magnesium-catalysed hydroboration and reductive C Created by potrace 1.16, written by Peter Selinger 2001-2019 O cleavage of organic isocyanates.

Inline graphic
Entry Ar/R Catalyst (mol%) Time (h) Temp (°C) NMR conv. a (%)
1 i-Pr 10 1.5 60 76
2 Ad 10 4.5 60 75
3 Et 10 21 60 70
4 n-Pr 10 21 60 75
5 t-Bu 10 3.5 60 81
6 Cy 10 4.5 60 90
7 Ph 10 24 25 86
8 Mes 10 24 60 90
9 Dipp 10 24 60 50

aTo N-methyl amine product.