Scheme 1. Synthesis of 1Ln, [NnPr4][Ln{Pt(SAc)4}2], and 2Ln from the dianionic platinum metalloligand [PtII(SAc)4]2– (SAc– = thioacetate), and of 1Ln′, [NnPr4][Ln{Pd(SAc)4}2], and 2Ln′ from the analogous palladium-based ligand.
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