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. 2018 Summer;17(3):1057–1067.

Table 1.

Compounds assigned in the G. glabra extract by LC-MS.

No Rt. (min) UV (nm) Identification [M-H] - MS 2 product ions (relative intensity) [M+H] +
1 13.6 230, 280 Dihydroxy-glabridin 357 135, 235, 339 341
2 17 230, 280, 340 Hydroxy-glabrene 337 161, 268, 293, 309, 322 339
3 18 220,280 Hydroxy-4’-O-methylglabridin 353 165, 201, 321, 309, 338 355
4 19.8 217, 250, 285, 325 Glabrene 321 175, 293, 306 323
5 25.5 280 Hydroxy-glabridin 339 135,203,221,321 341
6 26 230, 280 Glabridin 323 121, 135, 201 325
7 27 222, 250, 302 Glabrone 335 213, 291, 292, 307, 320 337
8 36 230, 280, 290 Hispaglabridin A 391 335 393
9 46 230, 280, 320 Hispaglabridin B 389 373 391