Table 1.
No | Rt. (min) | UV (nm) | Identification | [M-H] - | MS 2 product ions (relative intensity) | [M+H] + |
---|---|---|---|---|---|---|
1 | 13.6 | 230, 280 | Dihydroxy-glabridin | 357 | 135, 235, 339 | 341 |
2 | 17 | 230, 280, 340 | Hydroxy-glabrene | 337 | 161, 268, 293, 309, 322 | 339 |
3 | 18 | 220,280 | Hydroxy-4’-O-methylglabridin | 353 | 165, 201, 321, 309, 338 | 355 |
4 | 19.8 | 217, 250, 285, 325 | Glabrene | 321 | 175, 293, 306 | 323 |
5 | 25.5 | 280 | Hydroxy-glabridin | 339 | 135,203,221,321 | 341 |
6 | 26 | 230, 280 | Glabridin | 323 | 121, 135, 201 | 325 |
7 | 27 | 222, 250, 302 | Glabrone | 335 | 213, 291, 292, 307, 320 | 337 |
8 | 36 | 230, 280, 290 | Hispaglabridin A | 391 | 335 | 393 |
9 | 46 | 230, 280, 320 | Hispaglabridin B | 389 | 373 | 391 |